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Wednesday 24 December 2014

Conformational control of anticancer activity: the application of arene-linked dinuclear ruthenium(II) organometallics†

image file: c4sc00116h-f3.tif












Fig. 3 
1H NMR spectra of 4a (top) and 5a (bottom) (D2O, 400 MHz, 298 K, 10 mM).
Resonances are identified with coloured circles: linker phenyl – red, Ru arene – blue, CH – green, PTA – orange, CH2 – black and CH3 – purple.






image file: c4sc00116h-s1.tif
Scheme 1 Synthesis and numbering scheme of the mononuclear oxalato-complex 2a
dinuclear oxalato-complexes 3a–6a and chlorido-analogues 2b–6b.
/////////////////http://pubs.rsc.org/en/content/articlehtml/2014/sc/c4sc00116h///////////////




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